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Preparation and Spectroscopic Study of New NS Ligand and its Cd(II) and Zn(II) Metal Complexes | ||
| Journal of Al-Nahrain University - Science | ||
| Article 1, Volume 16, Issue 3, 2013, Pages 72-78 | ||
| Author | ||
| Hamsa Thamer Sadeq | ||
| Abstract | ||
| A new nitrogen sulphur Schiff base has been prepared from the condensation 1-(pyridin-4-yl) ethanone with 3-methylbenzyl hydrazinecarbodithioate leading the formation of new ligand 3-methylbenzyl (2Z)-2-[1-(pyridin-4-yl)ethylidene]hydrazine carbodithioate (PE3MBC). The ligand was reacted with Cd(II) and Zn(II) metal salts to form new coordinated complexes. The new ligand and its metal complexes were characterized via various physico-chemical and spectroscopic techniques and conductivity, magnetic susceptibility of metal complexes based on the data analysis the metal complexes are expected to be tetrahedral in geometry. | ||
| Keywords | ||
| Schiff Base; Pyridine; Zinc; cadmium | ||
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