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Synthesis and spectroscopic studies of new leucine acid derivative with their metal complexes. | ||
| Journal of University of Anbar for Pure Science | ||
| Article 17, Volume 7, Issue 1, 2013, Pages 66-73 PDF (537.53 K) | ||
| Document Type: Research Paper | ||
| DOI: 10.37652/juaps.2013.83185 | ||
| Authors | ||
| Muhammed Ahmed.Awaad1; Basima M.Sarhan2; Abdul Sattar Z.Khalaf* 1 | ||
| 1University of Anbar- Collage of Education for pure sciences | ||
| 2University Of Baghdad-Ibn-Al-Haitham Education collage. | ||
| Abstract | ||
| A new ligand N-[(acetyl amino)-thioxo methyl]leucine(ATL) are synthesized by reaction of acetyl-isothio cyanate with leucine acid. The ligand is characterized by elemental analysis, FT-IR and NMR spectra, some transition metal complex of this ligand were prepared and characterized by FT-IR, UV-visible spectra, conductively measurements, magnatic suscpility, atomic absorption and determination of molar ration(M:L). from results obtained, the following formaula [M(ATL)2] where M+2 =(Mn, Fe, Co, Ni, Cu, Zn, Cd and Hg) and the proposed molecular structure for these complexes as tetrahedral geometry. | ||
| Keywords | ||
| Leucine; acetyl isothiocyanate; Transition metals | ||
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